Partial oxidation kinetics of the mixture of acetic acid, phenol and naphthalene in supercritical water for hydrogen production

doi:10.1016/j.ijhydene.2017.06.102

	Partial oxidation kinetics of the mixture of acetic acid, phenol and naphthalene in supercritical water for hydrogen production
	Wang, Yuzhen; Gao, Fen ; Yang, Jianqiao ; Guo, Yang ; Zhu, Yitong ; Zhao, Gaoyang ; Fang, Changqing ; Guo, Yanfeng ; Wang, Shuzhong ; Guo, Ning
	2017-08-03
发表期刊	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷号	42 期号:31 页码:19843-19850
摘要	A quantitative kinetic model for the supercritical water partial oxidation of the mixture of acetic acid, naphthalene and phenol at 560 degrees C, 25 MPa was established. The model consisted a group of pathways that included two kind of compounds, which could be classified as stable cyclic compound (Int.1) and unstable ring-opening products (Int.2). The model was validated with the experimental data at oxygen ratio (OR) of 0 and 0.2, respectively. Results showed that the model could accurately predict the influences of reactants time on gas yields and intermediates concentrations. Reaction rate analysis indicated that the general trends of reaction rate at OR = 0 and OR = 0.2 were similar. The decomposition and steam reforming reactions of Int.2 were the main pathways for gas production. The oxygen during the gasification played a positive role in promoting the ring-opening reactions, which induced higher Int.2 production and increasing of steam reforming and decomposition rates, and finally increased the H-2 production. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
关键词	Supercritical water Partial oxidation Kinetics Acetic acid Phenol Naphthalene
DOI	10.1016/j.ijhydene.2017.06.102
收录类别	SCI ; EI ; SCOPUS ; SCIE
ISSN	0360-3199
语种	英语
WOS研究方向	Chemistry ; Electrochemistry ; Energy & Fuels
WOS类目	Chemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS记录号	WOS:000408180900026
出版者	PERGAMON-ELSEVIER SCIENCE LTD
EI入藏号	20172703898569
原始文献类型	Article
EISSN	1879-3487
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.lzufe.edu.cn/handle/39EH0E1M/11853
专题	信息工程与人工智能学院国际经济与贸易学院
作者单位	1.Xian Univ Technol, Xian 710048, Shaanxi, Peoples R China; 2.Xi An Jiao Tong Univ, Key Lab Thermofluid Sci & Engn MOE, Xian 710049, Shaanxi, Peoples R China; 3.Lanzhou Univ Finance & Econ, Inst Int Econ & Trade, Lanzhou 730030, Gansu, Peoples R China
推荐引用方式 GB/T 7714	Wang, Yuzhen,Gao, Fen,Yang, Jianqiao,et al. Partial oxidation kinetics of the mixture of acetic acid, phenol and naphthalene in supercritical water for hydrogen production[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(31):19843-19850.
APA	Wang, Yuzhen.,Gao, Fen.,Yang, Jianqiao.,Guo, Yang.,Zhu, Yitong.,...&Guo, Ning.(2017).Partial oxidation kinetics of the mixture of acetic acid, phenol and naphthalene in supercritical water for hydrogen production.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(31),19843-19850.
MLA	Wang, Yuzhen,et al."Partial oxidation kinetics of the mixture of acetic acid, phenol and naphthalene in supercritical water for hydrogen production".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.31(2017):19843-19850.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
15506.pdf（1509KB）	期刊论文	出版稿	暂不开放	CC BY-NC-SA	请求全文